OK. Eventually worked out something. Not sure if its the best method but seems to work.
If you use javascript in the "before send" event you can find your settings in "this.service.__requestOptions.serviceSettings". Just add .YourParameterName and you'll have it.
I do this prior to the mappings and can dynamically change the value of what is being mapped in the requests via say a {URL}. You'd find that in this.service.__requestOptions.serviceSettings.URL
I'm doing this so I can have a path going to a "live" or production environment or to or a test environment thus keeping them completely separate. Can then also use for training purposes as well as development. I have a page on the log on screen that you can go to where you can toggle between either environment (at this stage defaults to and reverts back to production). If there is an easier way I'm open to suggestions